Amorphous means predictable shrink
With no crystallisation to vary, Ultem’s shrink is low and nearly the same in every direction, so a dimension moves less with gate position and packing than it would in PEEK or acetal. That makes it one of the easier resins to hold a tight molded dimension in — which is exactly why its failures tend to show up somewhere other than the drawing’s tolerance block.
Notch-sensitive: radius every internal corner
Ultem is strong and stiff, and it concentrates stress at a sharp internal corner far more than its datasheet strength suggests. A crack that starts at a corner does not care how good the bulk properties are. Give every internal corner a radius the tool can cut, and treat a sharp corner on an Ultem drawing as a question to ask before the steel is cut, not a feature to reproduce.
Molded-in stress is the hidden variable
Amorphous resins lock in the stress of filling and cooling, and it stays there until something releases it — a solvent, a cleaning agent, a thermal cycle. The part passes inspection and cracks later. A hot, well-controlled mold and a gate placed so the flow does not have to fight its way around the part are what keep that stress low, and for parts that will meet chemicals it is worth agreeing how residual stress will be checked.
It has to be dry
Ultem absorbs moisture from the air, and wet resin at melt temperature leaves splay and bubbles and loses strength. Drying is not optional and not a guess — it is a time and a temperature, checked, before every run. At micro shot sizes the material also sits in the machine for many cycles before it is used, which is one more reason the resin has to go in right.